9701 MCQ Solution 16
Question 16:
[Inorganic > Group 2]:
River water in a chalky
agricultural area may contain Ca2+, Mg2+, CO32-,
HCO3-, Cl- and NO3-
ions. In a waterworks, such water is treated by adding a calculated quantity of
calcium hydroxide.
What will be precipitated following
the addition of calcium hydroxide?
A CaCl2
B CaCO3
C MgCO3
D Mg(NO3)2
Reference: Past Exam Paper – November 2002 Paper 1 Q16
Solution 16:
Answer: B.
The question is asking what will be precipitated followed by
the addition of calcium hydroxide so you can expect there will be a reaction
with calcium hydroxide with the other ions, so you have two options calcium
chloride which is A and calcium carbonate which is B.
Since question is saying what will be precipitated, a precipitate
is a solid insoluble, so you are looking for something that is insoluble. If we
look at A its CACl2 which is soluble in water so this is will not precipitate
it will dissolve, because all chlorides are soluble in water except silver and
lead chlorides.
If we look at D its magnesium nitrate and all nitrates all soluble
so this is not an option.
If we look at C its MgCO3 which is also insoluble so we can
take that as an answer but since question asked what will be precipitated
followed by addition of calcium hydroxide so we are expecting a reaction of
calcium hydroxide with the other ions.
Calcium hydroxide will react with HCO3 which is acid base
reaction and calcium carbonate will form which is insoluble, all carbonates are
insoluble except group 1 carbonates and ammonium carbonates. Therefore answer
is B.
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