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9701 MCQ Solution 52

9701 MCQ Solution 52:

Question 52: [Physical > Reaction Kinetics]

It is often said that the rate of a typical reaction is roughly doubled by raising the temperature by 10 °C.

What explains this observation?

A   Raising the temperature by 10 °C doubles the average energy of each molecule.
B   Raising the temperature by 10 °C doubles the average velocity of the molecules.
C   Raising the temperature by 10 °C doubles the number of molecular collisions in a given time.
D  Raising the temperature by 10 °C doubles the number of molecules having more than a certain minimum energy

Reference: Past Exam Paper -June 2003 Paper 1 Q12

Solution 52:

Answer: D.

A cannot be answer because indeed the temperature increases the average energy of molecules but not for each molecules , there will always be some molecules who won’t show an increase in energy
B cannot be answer because again indeed the temperature increases the average energy of molecules therefore molecules velocity will increase but the average velocity of molecules isn’t doubled by raising the temperature by 10 °C it just increases but not doesn’t double.
C cannot be answer because again raising the temperature by 10 °C  doesn’t double the average velocity of molecules or double the average energy or double the collision it just increase it.
D is the answer because it says the number of molecules having more than the activation energy is doubled therefore the reaction is doubled this therefore is a better answer because the molecules themselves have energy > activation energy are doubled therefore the rate of reaction is doubled.

9701 MCQ Solution 12

Question 12: [Physical > Reaction Kinetics]:
A piece of zinc foil dissolved completely in 20cm3 of a dilute sulphuric acid solution and the volume of hydrogen evolved was noted at equal, short time intervals. Another piece of zinc foil of the same surface area and mass was added to 40cm3 of the same solution of dilute sulphuric acid.

How will the initial rate of reaction and the total volume of hydrogen evolved in this second experiment compare to the first experiment?


initial rate of reaction
total volume of hydrogen evolved
A
no change
                   decrease
B
no change
                   no change
C
increase
                   no change
D
increase
                   increase

Reference: Past Exam Paper – November 2002 Paper 1 Q12



Solution 12:
Answer: B.

In the first experiment the piece of zinc foil completely dissolved in the 20cm3 solution. Thus we know that the solution is in excess already. Increasing the amount of solution will not produce more hydrogen gas since the amount of zinc, the limiting reactant, is still the same. Thus options A and D are eliminated. 
The zinc metal used in the second experiment had the same surface area as the piece of metal in the first experiment. This means that the contact point on which reactions can occur for both experiments are the same. Hence the rate of the reaction remains the same. This eliminates option C, leaving option B as the correct answer.